| Unlockable: | How to Unlock: |
| Hitsugaya School Costume | Win 15 matches with Toushiro Hitsugaya |
| Ikkaku School Costume | Win 10 matches with Madarame Ikkaku |
| Masked Komamura Costume | Win 15 matches with Komamura Sajin |
| Matsumoto School Costume | AFTER unlocking Inoue Orihime's costume, win 15 matches with Matsumoto Rangiku |
| Orihime School Costume | Win 15 matches with Inoue Orihime |
| Renji School Costume | Win 15 matches with Abarai Renji |
| Rukia School Costume | Win 15 matches with Kuchiki Rukia |
| Shihouin Yoruichi Shunpo Costume | After completing practice mode, win 15 matches with Yoruichi |
| Urahara Kisuke Shinigami Costume | Unlock everything, It becomes available for free in Urahara's Shop |
| Yumichika School Costume | Win 10 matches with Ayasegawa Yumichika |
| Unlockable: | How to Unlock: |
| Aizen Sousuke | Clear Arcade Mode with Ulquiorra |
| Arturo Plateado | Clear Episode Mode with Arturo Plateado |
| Grimmjow Jaggerjack | Clear Arcade Mode with Aizen Sousuke |
| Hinamori Momo | Clear Hitsugaya Toushiro's story |
| Hisagi Shuuhei | Clear Episode Mode with Yamada Hanatarou |
| Ichimaru Gin | Clear Arcade Mode with Matsumoto Rangiku and Kira Izuru |
| Kuchiki Rukia | Beat Story mode with Abarai Renji |
| Kurotsuchi Mayuri | Clear Arcade Mode with Ishida Uryuu |
| Kusajishi Yachiru | Clear Arcade Mode with Yumichika Ayasegawa and Zaraki Kenpachi |
| Kyouraku Shunsui | Clear Arcade Mode with Sado Yasutora |
| Madarame Ikkaku | Clear Episode Mode with Zaraki Kenpachi |
| Shihouin Yoruichi | Clear Training Mode |
| Soi Fon | Clear Episode Mode with Shihouin Yoruichi |
| Tousen Kaname | Clear Arcade Mode with Komamura Sajin |
| Ukitake Juushiro | Clear Arcade Mode with Kyouraku Shunsui |
| Ulquiorra | Clear Arcade Mode with Ichimaru Gin |
| Urahara Kisuke | Clear Arcade Mode with Kurotsuchi Mayuri |
| Yamada Hanatarou | Beat Story Mode with Youshiro Hitsugaya. |
| Yamamoto Genryuusai Shigekuni | Clear Arcade Mode with Ukitake Juushiro |
| Yumichika Ayasegawa | Clear Arcade Mode with Madarame Ikkaku |
